{"id":615,"date":"2023-12-14T14:59:52","date_gmt":"2023-12-14T06:59:52","guid":{"rendered":"https:\/\/factory.sslab.org.cn\/sxxjdc\/?p=615"},"modified":"2023-12-14T15:45:40","modified_gmt":"2023-12-14T07:45:40","slug":"%e7%a7%91%e7%a0%94%e8%bf%9b%e5%b1%95%e5%8f%af%e6%89%a9%e5%b1%95%e7%9a%84%e8%87%aa%e7%bb%84%e8%a3%85%e7%a1%ab%e9%86%87%e5%b1%82%e6%8a%91%e5%88%b6%e6%9e%9d%e6%99%b6%e5%bd%a2%e6%88%90%e5%92%8c%e7%94%b5","status":"publish","type":"post","link":"https:\/\/factory.sslab.org.cn\/sxxjdc\/blog\/2023\/12\/14\/%e7%a7%91%e7%a0%94%e8%bf%9b%e5%b1%95%e5%8f%af%e6%89%a9%e5%b1%95%e7%9a%84%e8%87%aa%e7%bb%84%e8%a3%85%e7%a1%ab%e9%86%87%e5%b1%82%e6%8a%91%e5%88%b6%e6%9e%9d%e6%99%b6%e5%bd%a2%e6%88%90%e5%92%8c%e7%94%b5\/","title":{"rendered":"\u79d1\u7814\u8fdb\u5c55|\u53ef\u6269\u5c55\u7684\u81ea\u7ec4\u88c5\u786b\u9187\u5c42\u6291\u5236\u679d\u6676\u5f62\u6210\u548c\u7535\u6781\u8150\u8680\u5b9e\u73b0\u7a33\u5b9a\u7684\u6c34\u7cfb\u950c\u7535\u6c60"},"content":{"rendered":"\n<p class=\"has-medium-font-size\">        \u8fd1\u5e74\u6765\uff0c\u867d\u7136\u9502\u79bb\u5b50\u7535\u6c60\u88ab\u8ba4\u4e3a\u662f\u50a8\u80fd\u7cfb\u7edf\u7684\u91cd\u8981\u91cc\u7a0b\u7891\uff0c\u4f46\u662f\u7531\u4e8e\u78b1\u91d1\u5c5e\u6750\u6599\u4f9b\u5e94\u6709\u9650\u3001\u6210\u672c\u9ad8\u4ee5\u53ca\u6613\u71c3\u6709\u673a\u7535\u89e3\u8d28\u548c\u9ad8\u6d3b\u6027\u9502\u6240\u5f15\u53d1\u7684\u5b89\u5168\u95ee\u9898\uff0c\u5b83\u4eec\u7684\u5e94\u7528\u53d7\u5230\u4e86\u4e00\u5b9a\u7684\u9650\u5236\u3002\u7531\u4e8e\u950c(Zn)\u91d1\u5c5e\u9633\u6781\u5177\u6709\u9ad8\u5929\u7136\u4e30\u5ea6\u3001\u4f4e\u6bd2\u6027\u3001\u4f4e\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u548c\u9ad8\u7406\u8bba\u5bb9\u91cf\uff0c\u6c34\u6027\u950c\u79bb\u5b50\u7535\u6c60(AZIB)\u5f15\u8d77\u4e86\u6781\u5927\u7684\u5173\u6ce8\u3002\u7136\u800c\uff0c\u679d\u6676\u751f\u957f\u3001\u9633\u6781\u8150\u8680\u548c\u6c34\u6eb6\u6db2\u4e2d\u7684\u6790\u6c22\u53cd\u5e94\u4e25\u91cd\u963b\u788d\u4e86\u91d1\u5c5e\u950c\u7684\u5e7f\u6cdb\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u8feb\u5207\u9700\u8981\u5bfb\u627e\u4e00\u79cd\u7b80\u5355\u3001\u6613\u64cd\u4f5c\u3001\u4f4e\u6210\u672c\u3001\u9ad8\u5b89\u5168\u6027\u548c\u53ef\u6269\u5c55\u7684\u65b9\u6cd5\u6765\u63d0\u9ad8\u950c\u9633\u6781\u7684\u7a33\u5b9a\u6027\u548c\u53ef\u9006\u6027\u3002<\/p>\n\n\n\n<p class=\"has-medium-font-size\">        \u7531\u4e8e\u5206\u5b50\u81ea\u7ec4\u88c5\u5c42\u5176\u72ec\u7279\u7684\u5934\u57fa\u56e2\u4e0e\u5e95\u7269\u4e4b\u95f4\u7684\u5f3a\u5316\u5b66\u952e\uff0c\u5206\u5b50\u5c3a\u5ea6\u7684\u539a\u5ea6\u4ee5\u53ca\u5206\u5b50\u5355\u5c42\u5185\u7684\u6709\u5e8f\u987a\u5e8f\u7b49\u6027\u80fd\u4f7f\u5176\u5728\u8bb8\u591a\u9886\u57df\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\u3002\u6211\u4eec\u5229\u7528\u4e00\u79cd\u7b80\u5355\u4e14\u5177\u6709\u5de5\u4e1a\u5316\u6269\u5c55\u6f5c\u529b\u7684\u89e3\u51b3\u65b9\u6cd5\uff0c\u5f00\u53d1\u4e86\u4e00\u79cd\u9ad8\u5ea6\u6709\u5e8f\u7684\u758f\u6c34\u6027\u81ea\u7ec4\u88c5\u786b\u9187\u5c42(SAML)\uff0c\u4ee5\u6291\u5236\u679d\u6676\u5f62\u6210\u3001\u91d1\u5c5e\u950c\u8150\u8680\u548c\u6790\u6c22\u53cd\u5e94\uff0c\u4ece\u800c\u7a33\u5b9a\u950c\u91d1\u5c5e\u8868\u9762\uff0c\u5ef6\u957f\u7535\u6c60\u5bff\u547d\u3002\u56e0\u6b64\uff0cHT-Zn||HT-Zn\u5bf9\u79f0\u7535\u6c60\u5728\u5404\u79cd\u7535\u6d41\u5bc6\u5ea6\u4e0b\u90fd\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\u3002\u8fd9\u79cd\u7a33\u5b9a\u6027\u5728HT-Zn||I<sub>2<\/sub>\u786c\u5e01\u7535\u6c60\u548c\u9ad8\u8d1f\u8f7d\u8f6f\u5305\u7535\u6c60(\u4f7f\u7528\u53ef\u6269\u5c55\u6eb6\u6db2\u65b9\u6cd5\u5236\u5907)\u4e2d\u5f97\u5230\u4e86\u8fdb\u4e00\u6b65\u8bc1\u660e\uff1a\u524d\u8005\u57284 A g<sup>\u22121<\/sup>\u7684\u5ef6\u957f\u5145\u653e\u7535\u5468\u671f\u4e2d\u4fdd\u6301100%\u7684\u5bb9\u91cf\uff0c\u540e\u8005\u57281000\u6b21\u5faa\u73af\u540e\u4ecd\u4fdd\u6301\u774090%\u7684\u5bb9\u91cf\uff0c\u5e76\u4e14\u5176CE\u8d85\u8fc799.1%\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201cInhibiting Dendrite Formation and Electrode Corrosion via a Scalable Self-Assembled Mercaptan Layer for Stable Aqueous Zinc Batteries\u201d\u5728\u56fd\u9645\u8457\u540d\u671f\u520aAdvanced Energy Materials\u4e0a\u53d1\u8868\u3002<strong>\u4efb\u5b9d\u5349\uff08\u677e\u5c71\u6e56\u6750\u6599\u5b9e\u9a8c\u5ba4\u4e0e\u6df1\u5733\u5927\u5b66\u8054\u5408\u57f9\u517b\u535a\u58eb\u540e\uff09\u7b2c\u4e00\u4f5c\u8005\uff0c\u677e\u5c71\u6e56\u6750\u6599\u5b9e\u9a8c\u5ba4\u652f\u6625\u4e49\u7814\u7a76\u5458<\/strong>\uff0c<strong>\u5357\u65b9\u79d1\u6280\u5927\u5b66\u674e\u6d2a\u98de\u52a9\u7406\u6559\u6388\uff0c\u6df1\u5733\u5927\u5b66\u5218\u5353\u946b\u52a9\u7406\u6559\u6388\u4e3a\u8bba\u6587\u901a\u8baf\u4f5c\u8005<\/strong>\u3002<\/p>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full is-resized\"><img decoding=\"async\" loading=\"lazy\" width=\"681\" height=\"436\" src=\"https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-content\/uploads\/sites\/19\/2023\/12\/image-8.png\" alt=\"\" class=\"wp-image-616\" style=\"aspect-ratio:1.561926605504587;object-fit:cover;width:900px\" srcset=\"https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-content\/uploads\/sites\/19\/2023\/12\/image-8.png 681w, https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-content\/uploads\/sites\/19\/2023\/12\/image-8-300x192.png 300w\" sizes=\"(max-width: 681px) 100vw, 681px\" \/><figcaption class=\"wp-element-caption\"><strong>\u56fe1 Zn\u4e0aHT-SAML\u7684\u8868\u5f81<\/strong><\/figcaption><\/figure><\/div>\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full is-resized\"><img decoding=\"async\" loading=\"lazy\" width=\"693\" height=\"509\" src=\"https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-content\/uploads\/sites\/19\/2023\/12\/image-9.png\" alt=\"\" class=\"wp-image-617\" style=\"aspect-ratio:1.3614931237721022;object-fit:cover;width:900px\" srcset=\"https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-content\/uploads\/sites\/19\/2023\/12\/image-9.png 693w, https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-content\/uploads\/sites\/19\/2023\/12\/image-9-300x220.png 300w\" sizes=\"(max-width: 693px) 100vw, 693px\" \/><figcaption class=\"wp-element-caption\"><strong>\u56fe2 HT\u5206\u5b50\u7684\u6a21\u62df<\/strong><\/figcaption><\/figure><\/div>\n\n\n<p class=\"has-medium-font-size\">        \u56fe1a\u5c55\u793a\u4e86HT\u5728Zn\u4e0a\u7684\u539f\u4f4d\u81ea\u7ec4\u88c5\u8fc7\u7a0b\u3002\u5def\u57fa\u4e0eZn\u53d1\u751f\u53cd\u5e94\u5f62\uff0c\u6210\u7a33\u5b9a\u7684Zn\u2212S\u952e\u3002\u540c\u65f6\uff0c\u70f7\u57fa\u94fe\u4ee5\u5782\u76f4\u6392\u5217\u7684\u65b9\u5f0f\u5f62\u6210\u6709\u5e8f\u7d27\u5bc6\u7684\u7ed3\u6784\uff0c\u4ece\u800c\u5728Zn\u8868\u9762\u5f62\u6210\u758f\u6c34\u754c\u9762\u5c42(HT-Zn\u8868\u793a\u6240\u5f97\u7684Zn\u7535\u6781)\u3002\u8fd9\u79cd\u7b80\u4fbf\u3001\u7ecf\u6d4e\u7684SAML\u5236\u5907\u5de5\u827a\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u5177\u6709\u5927\u89c4\u6a21\u5408\u6210\u7684\u53ef\u884c\u6027\u3002\u901a\u8fc7FTIR\u3001Raman\u548cXPS\u7b49\u9a8c\u8bc1\u4e86\u5728Zn\u7535\u6781\u4e0a\u6210\u529f\u5236\u5907\u51faHT-SAML\u3002\u540c\u65f6\uff0c\u56fe2\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0cHT\u7684\u70f7\u57fa\u9aa8\u67b6\u5782\u76f4\u6392\u5217\u5728Zn\u91d1\u5c5e\u8868\u9762\uff0c\u5f62\u6210\u81f4\u5bc6\u3001\u9ad8\u5ea6\u6709\u5e8f\u7684\u7ed3\u6784\u3002<\/p>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full is-resized\"><img decoding=\"async\" loading=\"lazy\" width=\"980\" height=\"890\" src=\"https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-content\/uploads\/sites\/19\/2023\/12\/\u56fe\u72476.png\" alt=\"\" class=\"wp-image-618\" style=\"width:900px\" srcset=\"https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-content\/uploads\/sites\/19\/2023\/12\/\u56fe\u72476.png 980w, https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-content\/uploads\/sites\/19\/2023\/12\/\u56fe\u72476-300x272.png 300w, https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-content\/uploads\/sites\/19\/2023\/12\/\u56fe\u72476-768x697.png 768w\" sizes=\"(max-width: 980px) 100vw, 980px\" \/><figcaption class=\"wp-element-caption\"><strong>\u56fe3 \u950c\u9633\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/figcaption><\/figure><\/div>\n\n\n<p class=\"has-medium-font-size\">        \u56e0\u6b64\uff0c\u57281 mA cm<sup>\u22122<\/sup>\u548c0.5 mAh cm<sup>\u22122<\/sup>\u4e0b\uff0c\u91c7\u7528\u88f8Zn\u9633\u6781\u7684\u5bf9\u79f0\u7535\u6c60\u5728\u5faa\u73af777\u5c0f\u65f6\u540e\u7a81\u7136\u5931\u6548\uff0c\u51fa\u73b0\u5c40\u90e8\u77ed\u8def\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u7531\u4e8e\u5b58\u5728\u4fdd\u62a4\u6027\u7684HT-SAML\uff0cHT-Zn||HT-Zn\u5bf9\u79f0\u7535\u6c60\u8868\u73b0\u51fa\u9ad8\u5ea6\u53ef\u9006\u4e14\u7a33\u5b9a\u7684\u7535\u9540\/\u5265\u79bb\u6027\u80fd\uff0c\u5e76\u6301\u7eed\u8d85\u8fc71800\u5c0f\u65f6\u3002\u540c\u65f6\uff0cHT-Zn||HT-Zn\u5bf9\u79f0\u7535\u6c60\u7684\u8fc7\u7535\u4f4d\u4ec5\u7ea6\u4e3a63 mV\uff0c\u663e\u8457\u4f4e\u4e8eZn||Zn\u7535\u6c60\u7684\u8fc7\u7535\u4f4d\uff08114 mV\uff09\u3002<\/p>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full is-resized\"><img decoding=\"async\" loading=\"lazy\" width=\"693\" height=\"475\" src=\"https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-content\/uploads\/sites\/19\/2023\/12\/image-10.png\" alt=\"\" class=\"wp-image-619\" style=\"aspect-ratio:1.4589473684210525;object-fit:cover;width:900px\" srcset=\"https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-content\/uploads\/sites\/19\/2023\/12\/image-10.png 693w, https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-content\/uploads\/sites\/19\/2023\/12\/image-10-300x206.png 300w\" sizes=\"(max-width: 693px) 100vw, 693px\" \/><figcaption class=\"wp-element-caption\"><strong>\u56fe4 \u6291\u5236\u679d\u6676\u548c\u526f\u53cd\u5e94<\/strong><\/figcaption><\/figure><\/div>\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full is-resized\"><img decoding=\"async\" loading=\"lazy\" width=\"980\" height=\"805\" src=\"https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-content\/uploads\/sites\/19\/2023\/12\/\u56fe\u72477-1.png\" alt=\"\" class=\"wp-image-620\" style=\"aspect-ratio:1.2173913043478262;object-fit:cover;width:900px\" srcset=\"https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-content\/uploads\/sites\/19\/2023\/12\/\u56fe\u72477-1.png 980w, https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-content\/uploads\/sites\/19\/2023\/12\/\u56fe\u72477-1-300x246.png 300w, https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-content\/uploads\/sites\/19\/2023\/12\/\u56fe\u72477-1-768x631.png 768w\" sizes=\"(max-width: 980px) 100vw, 980px\" \/><figcaption class=\"wp-element-caption\"><strong>\u56fe5 HT\u7684\u9632\u8150\u673a\u5236<\/strong><\/figcaption><\/figure><\/div>\n\n\n<p class=\"has-medium-font-size\">        \u901a\u8fc7EIS\u3001Tafel\u548cLSV\u7b49\u6d4b\u8bd5\uff0c\u8bc1\u660e\u4e86HT-SAML\u5177\u6709\u51fa\u8272\u7684\u9632\u8150\u6027\u80fd\u548c\u6291\u5236\u6790\u6c22\u6027\u80fd\u3002\u63a5\u89e6\u89d2\u6d4b\u91cf\u548c\u7406\u8bba\u8ba1\u7b97\u7ed3\u679c\u8868\u660eHT-Zn\u5177\u6709\u4f18\u8d8a\u7684\u758f\u6c34\u6027\uff0c\u8fd9\u6709\u52a9\u4e8e\u4fdd\u62a4Zn\u9633\u6781\u514d\u53d7\u53d7\u6c34\u4fb5\u8680\uff0c\u5e76\u6291\u5236\u7535\u6781\u5904\u53d1\u751f\u7684\u6790\u6c22\u53cd\u5e94\u3002\u901a\u8fc7\u5728\u950c\u9633\u6781\u4e0a\u6784\u5efaHT-SAML\uff0c\u5728\u5206\u5b50\u6c34\u5e73\u4e0a\u6539\u53d8\u4e86\u754c\u9762\u6027\u8d28\uff0c\u5f62\u6210\u4e86\u4e00\u4e2a\u758f\u6c34\u6392\u65a5\u5c4f\u969c\uff0c\u9632\u6b62\u8150\u8680\u4ecb\u8d28\u4fb5\u5165\u5e76\u6291\u5236\u6c22\u6c14\u5728\u7535\u6781\u4e0a\u7684\u4ea7\u751f\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0cSAML\u72ec\u7279\u7684\u6709\u5e8f\u9aa8\u67b6\u4e5f\u53ef\u4ee5\u5f15\u5bfc\u5747\u5300\u7684Zn\u6c89\u79ef\uff0c\u4ece\u800c\u6291\u5236\u679d\u6676\u7684\u5f62\u6210\u3002<\/p>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full is-resized\"><img decoding=\"async\" loading=\"lazy\" width=\"980\" height=\"771\" src=\"https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-content\/uploads\/sites\/19\/2023\/12\/\u56fe\u72478.png\" alt=\"\" class=\"wp-image-621\" style=\"width:900px\" srcset=\"https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-content\/uploads\/sites\/19\/2023\/12\/\u56fe\u72478.png 980w, https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-content\/uploads\/sites\/19\/2023\/12\/\u56fe\u72478-300x236.png 300w, https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-content\/uploads\/sites\/19\/2023\/12\/\u56fe\u72478-768x604.png 768w\" sizes=\"(max-width: 980px) 100vw, 980px\" \/><figcaption class=\"wp-element-caption\"><strong>\u56fe6 Zn||I<sub>2<\/sub>\u548cHT-Zn||I<sub>2<\/sub>\u5168\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/figcaption><\/figure><\/div>\n\n\n<p class=\"has-medium-font-size\">        \u5728\u5168\u7535\u6c60\u6027\u80fd\u65b9\u9762\uff0c\u4f7f\u7528\u88f8Zn\u9633\u6781\u7684\u5168\u7535\u6c60\u5728\u6700\u521d\u7684100\u6b21\u5faa\u73af\u4e2d\u653e\u7535\u5bb9\u91cf\u8fc5\u901f\u8870\u51cf\uff0c\u5728\u968f\u540e\u7684\u5faa\u73af\u4e2d\u653e\u7535\u5bb9\u91cf\u9010\u6e10\u4e0b\u964d\uff0c\u57281500\u6b21\u5faa\u73af\u540e\u751a\u81f3\u4f4e\u81f369 mAh g<sup>\u22121<\/sup>\u3002\u4e0e\u6b64\u5f62\u6210\u9c9c\u660e\u5bf9\u6bd4\u7684\u662f\uff0cHT-Zn||I<sub>2<\/sub>\u5168\u7535\u6c60\u5728\u8d85\u8fc71500\u6b21\u5faa\u73af\u4e2d\u8868\u73b0\u51fa\u51fa\u8272\u7684\u8d85\u7a33\u5b9a\u6027\uff0c\u5728\u6269\u5c55\u5145\u653e\u7535\u6d4b\u8bd5\u4e2d\u6ca1\u6709\u660e\u663e\u7684\u5bb9\u91cf\u8870\u51cf\uff0c\u653e\u7535\u5bb9\u91cf\u4fdd\u6301\u572890 mAh 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