{"id":496,"date":"2023-12-07T11:18:16","date_gmt":"2023-12-07T03:18:16","guid":{"rendered":"https:\/\/factory.sslab.org.cn\/sxxjdc\/?p=496"},"modified":"2023-12-12T14:55:04","modified_gmt":"2023-12-12T06:55:04","slug":"%e5%9f%ba%e4%ba%8e%e8%bd%ac%e5%8c%96%e5%8f%8d%e5%ba%94%e5%8c%96%e5%ad%a6%e7%9a%84%e9%ab%98%e5%80%8d%e7%8e%87%e6%b0%b4%e7%b3%bb%e9%93%9d-%e7%a2%98%e7%94%b5%e6%b1%a0","status":"publish","type":"post","link":"https:\/\/factory.sslab.org.cn\/sxxjdc\/blog\/2023\/12\/07\/%e5%9f%ba%e4%ba%8e%e8%bd%ac%e5%8c%96%e5%8f%8d%e5%ba%94%e5%8c%96%e5%ad%a6%e7%9a%84%e9%ab%98%e5%80%8d%e7%8e%87%e6%b0%b4%e7%b3%bb%e9%93%9d-%e7%a2%98%e7%94%b5%e6%b1%a0\/","title":{"rendered":"\u57fa\u4e8e\u8f6c\u5316\u53cd\u5e94\u5316\u5b66\u7684\u9ad8\u500d\u7387\u6c34\u7cfb\u94dd-\u7898\u7535\u6c60"},"content":{"rendered":"\n<p>\u79bb\u5b50\u6db2\u4f53\u7531\u4e8e\u5176\u8f83\u5bbd\u7684\u7535\u5316\u5b66\u7a97\u53e3\u548c\u53ef\u9006\u7684\u94dd\u6c89\u79ef\/\u6eb6\u89e3\u800c\u6210\u4e3a\u94dd\u79bb\u5b50\u7535\u6c60\uff08AIBs\uff09\u4e2d\u4f7f\u7528\u6700\u5e7f\u6cdb\u7684\u7535\u89e3\u8d28\u3002\u7136\u800c\uff0c\u5176\u9020\u6210\u7684\u73af\u5883\u95ee\u9898\u3001\u4e25\u683c\u7684\u64cd\u4f5c\u6761\u4ef6\u548c\u8150\u8680\u6027\u963b\u788d\u4e86\u5b83\u4eec\u7684\u5b9e\u9645\u5e94\u7528\u3002\u4e0e\u79bb\u5b50\u6db2\u4f53\u76f8\u6bd4\uff0c\u6c34\u7cfb\u94dd\u79bb\u5b50\u7535\u6c60\u7531\u4e8e\u5176\u6210\u672c\u4f4e\u5ec9\u548c\u5b89\u5168\u6027\uff0c\u662f\u4e0b\u4e00\u4ee3\u50a8\u80fd\u7cfb\u7edf\u7684\u7406\u60f3\u9009\u62e9\u3002\u76ee\u524d\u62a5\u5bfc\u7684\u6c34\u7cfb\u94dd\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u90fd\u662f\u57fa\u4e8e\u79bb\u5b50\u7684\u5d4c\u5165\/\u8131\u51fa\u673a\u5236\uff0c\u5728\u8fd9\u4e2a\u8fc7\u7a0b\u4e2d\uff0cAl<sup>3+<\/sup>\u8f83\u5927\u7684\u5e93\u4f26\u65a5\u529b\u5bb9\u6613\u5bfc\u81f4\u6b63\u6781\u6750\u6599\u7684\u574d\u584c\uff0c\u56e0\u6b64\u5b58\u5728\u500d\u7387\u6027\u80fd\u8f83\u5dee\uff0c\u5faa\u73af\u6b21\u6570\u4f4e\u7b49\u95ee\u9898\u3002\u56e0\u6b64\uff0c\u9009\u62e9\u4e00\u79cd\u57fa\u4e8e\u8f6c\u5316\u53cd\u5e94\u673a\u5236\u7684\u6c34\u7cfb\u94dd\u79bb\u5b50\u7535\u6c60\u6750\u6599\u6765\u66ff\u4ee3\u76ee\u524d\u57fa\u4e8e\u79bb\u5b50\u5d4c\u5165\/\u8131\u51fa\u673a\u5236\u7684\u6b63\u6781\u6750\u6599\u52bf\u5728\u5fc5\u884c\u3002\u5176\u4e2d\uff0c\u7898\u5355\u8d28\u6709\u7740\u5f88\u9ad8\u7684\u7406\u8bba\u5bb9\u91cf\u4ee5\u53ca\u4e30\u5bcc\u7684\u8d44\u6e90(\u6d77\u6c34\u542b\u91cf50-60 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I<sup>&#8211;<\/sup>\uff09\u3002\u7531\u4e8e&nbsp;\u201cwater-in-salt\u201d\u6c34\u7cfb\u7535\u89e3\u6db2\u53ef\u4ee5\u5e2e\u52a9\u89e3\u51b3\u79bb\u5b50\u6db2\u4f53\u79bb\u5b50\u7535\u5bfc\u7387\u4f4e\uff0c\u6781\u5316\u5927\u7b49\u95ee\u9898\uff0c\u6c34\u7cfb\u94dd-\u7898\u7535\u6c60\u6709\u7740\u66f4\u9ad8\u7684\u7535\u538b\u5e73\u53f0\u548c\u66f4\u5927\u7684\u653e\u7535\u5bb9\u91cf\u3002\u6b64\u5916\uff0c\u5c06\u6613\u6eb6\u89e3\u7684\u7898\u9650\u57df\u5728\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u884d\u751f\u7684\u6c2e\u63ba\u6742\u591a\u5b54\u78b3\u4e2d\uff08I<sub>2<\/sub>@ZIF-8-C\uff09\uff0c\u80fd\u591f\u6709\u6548\u5730\u63d0\u9ad8\u7898\u7684\u70ed\u529b\u5b66\u7a33\u5b9a\u6027\uff0c\u83b7\u5f97\u7a33\u5b9a\u7684\u56fa-\u6db2\u8f6c\u5316\u53cd\u5e94\u3002\u6240\u5f97\u5230\u6c34\u7cfb\u94dd-\u7898\u7535\u6c60\u5177\u8f83\u9ad8\u7684\u653e\u7535\u6bd4\u5bb9\u91cf&nbsp;(219.8 mAh g<sup>-1<\/sup>) \u548c\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd (8A 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EDS\u80fd\u8c31\u56fe<\/figcaption><\/figure><\/div>\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter\"><img decoding=\"async\" src=\"https:\/\/www.sslab.org.cn\/uploads\/%E7%A7%91%E7%A0%94%E8%BF%9B%E5%B1%95\/20211014\/%E5%9B%BE%E7%89%87%203_%E5%89%AF%E6%9C%AC800.png\" alt=\"\" \/><figcaption class=\"wp-element-caption\">\u56fe2.\u00a0I<sub>2<\/sub>@ZIF-8-C\u548cZIF-8-C\u7684\u00a0(a)\u00a0\u6c2e\u6c14\u5438\u9644\u66f2\u7ebf\u548c(b) XPS\u56fe\uff1b\uff08c\uff09\uff0c\uff08d\uff09\u4e0d\u540c\u5143\u7d20\u9ad8\u5206\u8fa8XPS\u56fe\uff1b\u00a0(e) I<sub>2<\/sub>@ZIF-8-C\u548cZIF-8-C\u6837\u54c1\u7684\u70ed\u91cd\u66f2\u7ebf\uff1b\uff08f\uff09\u4e0d\u540c\u6837\u54c1\u7684\u6eb6\u89e3\u7387\u548c\u5149\u5b66\u7167\u7247\u3002<\/figcaption><\/figure><\/div>\n\n\n<h2 class=\"wp-block-heading\">2. 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Al<sub>2<\/sub>Cl<sub>7<\/sub>-\u9634\u79bb\u5b50\u5728\u7535\u6c89\u79ef\u8fc7\u7a0b\u4e2d\u7531\u4e8e\u7535\u573a\u7684\u4f5c\u7528\u4f1a\u8fdc\u79bb\u94dd\u8d1f\u6781\uff0c\u4ece\u800c\u5bfc\u81f4\u4e25\u91cd\u7684\u7535\u6c60\u6781\u5316\u3002\u800c\u6c34\u7cfb\u7535\u89e3\u6db2\u7684\u4f7f\u7528\u5219\u80fd\u591f\u5e2e\u52a9\u89e3\u51b3\u4e0a\u8ff0\u4e24\u79cd\u95ee\u9898\uff0c\u4ece\u800c\u83b7\u5f97\u8f83\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u6b64\u5916\uff0c\u7531\u4e8eZIF-8-C\u8fde\u901a\u76843D\u5bfc\u7535\u7f51\u7edc\u548c\u9650\u57df\u7684\u6db2-\u56fa\u53cd\u5e94\uff0c\u94dd-\u7898\u7535\u6c60\u5177\u6709\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\u548c\u8f83\u597d\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u80fd\uff0c\u5176\u7535\u6c60\u6027\u80fd\u8d85\u8fc7\u4e86\u7edd\u5927\u591a\u6570\u4ee5\u94dd\u91d1\u5c5e\u4e3a\u8d1f\u6781\u7684\u6c34\u7cfb\u94dd\u79bb\u5b50\u7535\u6c60\u3002<\/p>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter\"><img decoding=\"async\" src=\"https:\/\/www.sslab.org.cn\/uploads\/%E7%A7%91%E7%A0%94%E8%BF%9B%E5%B1%95\/20211014\/%E5%9B%BE%E7%89%87%205_%E5%89%AF%E6%9C%AC800.png\" alt=\"\" \/><figcaption class=\"wp-element-caption\">\u56fe 3. (a) \u6c34\u7cfb\u94dd\u79bb\u5b50\u7535\u6c60\u793a\u610f\u56fe\uff1b(b) \u4e0d\u540c\u7535\u89e3\u6db2\u94dd-\u7898\u7535\u6c60\u6052\u6d41\u5145\u653e\u7535\u66f2\u7ebf\uff1b(c) Al\/\/I<sub>2<\/sub>@ZIF-8-C \u7535\u6c60\u5728\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u7684 CV \u66f2\u7ebf\uff1b\u00a0(d) \u6c34\u7cfb Al\/\/I<sub>2<\/sub>@ZIF-8-C \u7535\u6c60\u7684\u500d\u7387\u6027\u80fd\uff1b\u00a0\uff08e\uff09I<sub>2<\/sub>@ZIF-8-C\u6b63\u6781\u548c\u5176\u4ed6\u94dd\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u7684\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5bb9\u91cf\u5bf9\u6bd4\u56fe\u3002 I<sub>2<\/sub>\u548c I<sub>2<\/sub>@ZIF-8-C\u6b63\u6781\u7684\u00a0(f) EIS \u66f2\u7ebf\u548c (g) \u5faa\u73af\u6027\u80fd\u3002<\/figcaption><\/figure><\/div>\n\n\n<h2 class=\"wp-block-heading\">3. \u53cd\u5e94\u673a\u5236<\/h2>\n\n\n\n<p>\u901a\u8fc7\u4f7f\u7528\u62c9\u66fc\u5149\u8c31\u548cXPS\u6d4b\u8bd5\uff08\u56fe3\uff09\uff0c\u8bc1\u660e\u4e86I<sub>2<\/sub>@ZIF-8-C\u5728\u6c34\u7cfb\u94dd\u79bb\u5b50\u7535\u6c60\u7684\u53cd\u5e94\u673a\u5236\u4e3a\u8f6c\u5316\u53cd\u5e94\u673a\u5236\uff0c\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u4f34\u968f\u7740I<sub>2<\/sub>\u548cI<sup>&#8211;<\/sup>\u4e4b\u95f4\u7684\u53ef\u9006\u8f6c\u6362\uff0c\u5e76\u4e14\u5b58\u5728I<sub>5<\/sub>-\u548cI<sub>3<\/sub>-\u8fd9\u4e24\u79cd\u4e2d\u95f4\u4f53\u3002<\/p>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter\"><img decoding=\"async\" src=\"https:\/\/www.sslab.org.cn\/uploads\/%E7%A7%91%E7%A0%94%E8%BF%9B%E5%B1%95\/20211014\/%E5%9B%BE%E7%89%87%2018_%E5%89%AF%E6%9C%AC800.png\" alt=\"\" \/><figcaption class=\"wp-element-caption\">\u56fe4.\u00a0\u6c34\u7cfbAl\/\/I<sub>2<\/sub>@ZIF-8-C\u6c60\u7684\u53cd\u5e94\u673a\u7406\u3002<\/figcaption><\/figure><\/div>\n\n\n<h2 class=\"wp-block-heading\">4. \u67d4\u6027\u7535\u6c60\u5668\u4ef6<\/h2>\n\n\n\n<p>\u5f97\u76ca\u4e8e\u8be5\u7535\u6c60\u4f53\u7cfb\u7684\u4f18\u5f02\u7535\u5316\u5b66\u6027\u80fd\uff0c\u4f5c\u8005\u540c\u65f6\u4e5f\u5236\u5907\u4e86\u67d4\u6027\u7535\u6c60\u5668\u4ef6\u3002\u4ee5\u805a\u4e19\u70ef\u9178\uff08PAA\uff09\u4e3a\u51dd\u80f6\u7535\u89e3\u8d28\uff0c\u53ef\u4ee5\u83b7\u5f97\u4e0e\u6db2\u4f53\u7535\u6c60\u76f8\u5ab2\u7f8e\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u8bc1\u660e\u4e86\u8be5\u7535\u6c60\u4f53\u7cfb\u5728\u67d4\u6027\u7535\u6c60\u548c\u53ef\u7a7f\u6234\u8bbe\u5907\u5e94\u7528\u4e2d\u7684\u5de8\u5927\u6f5c\u529b\u3002<\/p>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter\"><img decoding=\"async\" src=\"https:\/\/www.sslab.org.cn\/uploads\/%E7%A7%91%E7%A0%94%E8%BF%9B%E5%B1%95\/20211014\/%E5%9B%BE%E7%89%87%208_%E5%89%AF%E6%9C%AC800.png\" alt=\"\" \/><figcaption class=\"wp-element-caption\">\u56fe 5. (a) \u67d4\u6027 Al\/\/I<sub>2<\/sub>@ZIF-8-C \u7535\u6c60\u793a\u610f\u56fe\uff1b(b) Al\/\/I<sub>2<\/sub>@ZIF-8-C \u4f7f\u7528\u6db2\u6001\u548c\u51dd\u80f6\u7535\u89e3\u8d28\u7684CV \u66f2\u7ebf\uff1b\u67d4\u6027Al\/\/I<sub>2<\/sub>@ZIF-8-C\u7535\u6c60\u7684\u00a0(c) \u500d\u7387\u6027\u80fd\u548c\u00a0(d) \u5faa\u73af\u6027\u80fd;\u00a0(e) \u67d4\u6027 Al\/\/I<sub>2<\/sub>@ZIF-8-C\u7535\u6c60\u4f9b\u7535\u7684\u667a\u80fd\u978b\u57ab\u7167\u7247\u3002 (f) \u7531\u67d4\u6027\u7535\u6c60\u4f9b\u7535\u7684\u667a\u80fd\u978b\u57ab\u8fdb\u884c\u8fd0\u52a8\u76d1\u6d4b\uff08\u5de6\uff09\u3001\u538b\u529b\u5206\u5e03\uff08\u4e2d\uff09\u548c\u8dd1\u6b65\u8def\u5f84\uff08\u53f3\uff09\u3002<\/figcaption><\/figure><\/div>\n\n\n<p>\u76f8\u5173\u7814\u7a76\u6210\u679c\u53d1\u8868\u5728\u56fd\u9645\u77e5\u540d\u671f\u520aSmall&nbsp;Methods\u4e0a\uff0c\u9633\u6714\uff0c\u674e\u5ddd\u548c\u5415\u6d77\u660e\u4e3a\u672c\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\uff0c\u677e\u5c71\u6e56\u6750\u6599\u5b9e\u9a8c\u5ba4\u674e\u6d2a\u98de\u526f\u7814\u7a76\u5458\u548c\u677e\u5c71\u6e56\u6750\u6599\u5b9e\u9a8c\u5ba4\/\u9999\u6e2f\u57ce\u5e02\u5927\u5b66\u652f\u6625\u4e49\u6559\u6388\u4e3a\u901a\u8baf\u4f5c\u8005\u3002\u6b64\u9879\u5de5\u4f5c\u5f97\u5230\u4e86\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u3001\u5e7f\u4e1c\u7701\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u7b49\u9879\u76ee\u7684\u5927\u529b\u652f\u6301\u3002<\/p>\n\n\n\n<div class=\"wp-block-buttons is-layout-flex wp-block-buttons-is-layout-flex\">\n<div class=\"wp-block-button\"><a class=\"wp-block-button__link wp-element-button\" href=\"https:\/\/www.sslab.org.cn\/news\/researchdetail?id=21101415004253609BB989C4E\">\u539f\u6587\u94fe\u63a5<\/a><\/div>\n<\/div>\n","protected":false},"excerpt":{"rendered":"<p>\u79bb\u5b50\u6db2\u4f53\u7531\u4e8e\u5176\u8f83\u5bbd\u7684\u7535\u5316\u5b66\u7a97\u53e3\u548c\u53ef\u9006\u7684\u94dd\u6c89\u79ef\/\u6eb6\u89e3\u800c\u6210\u4e3a\u94dd\u79bb\u5b50\u7535\u6c60\uff08AIBs\uff09\u4e2d\u4f7f\u7528\u6700\u5e7f\u6cdb\u7684\u7535\u89e3\u8d28\u3002\u7136\u800c\uff0c\u5176\u9020 [&hellip;]<\/p>\n","protected":false},"author":43,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[7],"tags":[],"acf":[],"_links":{"self":[{"href":"https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-json\/wp\/v2\/posts\/496"}],"collection":[{"href":"https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-json\/wp\/v2\/users\/43"}],"replies":[{"embeddable":true,"href":"https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-json\/wp\/v2\/comments?post=496"}],"version-history":[{"count":3,"href":"https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-json\/wp\/v2\/posts\/496\/revisions"}],"predecessor-version":[{"id":544,"href":"https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-json\/wp\/v2\/posts\/496\/revisions\/544"}],"wp:attachment":[{"href":"https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-json\/wp\/v2\/media?parent=496"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-json\/wp\/v2\/categories?post=496"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-json\/wp\/v2\/tags?post=496"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}