{"id":486,"date":"2023-12-07T11:10:43","date_gmt":"2023-12-07T03:10:43","guid":{"rendered":"https:\/\/factory.sslab.org.cn\/sxxjdc\/?p=486"},"modified":"2023-12-12T15:13:39","modified_gmt":"2023-12-12T07:13:39","slug":"%e7%a7%91%e7%a0%94%e8%bf%9b%e5%b1%95%e4%b8%a8%e5%90%a1%e5%97%aa%e5%92%8c%e5%90%a1%e5%95%b6%e8%83%ba%e5%8d%95%e5%85%83%e7%9a%84%e5%85%b1%e4%bb%b7%e6%9c%89%e6%9c%ba%e9%aa%a8%e6%9e%b6%ef%bc%88cof","status":"publish","type":"post","link":"https:\/\/factory.sslab.org.cn\/sxxjdc\/blog\/2023\/12\/07\/%e7%a7%91%e7%a0%94%e8%bf%9b%e5%b1%95%e4%b8%a8%e5%90%a1%e5%97%aa%e5%92%8c%e5%90%a1%e5%95%b6%e8%83%ba%e5%8d%95%e5%85%83%e7%9a%84%e5%85%b1%e4%bb%b7%e6%9c%89%e6%9c%ba%e9%aa%a8%e6%9e%b6%ef%bc%88cof\/","title":{"rendered":"\u79d1\u7814\u8fdb\u5c55\u4e28\u5421\u55ea\u548c\u5421\u5576\u80fa\u5355\u5143\u7684\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\uff08COF\uff09\u7528\u4e8e\u6c34\u7cfb\u9499\u79bb\u5b50\u7535\u6c60\u9633\u6781\u6750\u6599"},"content":{"rendered":"<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full\"><img decoding=\"async\" loading=\"lazy\" width=\"703\" height=\"335\" src=\"https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-content\/uploads\/sites\/19\/2023\/12\/image-1.png\" alt=\"\" class=\"wp-image-556\" srcset=\"https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-content\/uploads\/sites\/19\/2023\/12\/image-1.png 703w, https:\/\/factory.sslab.org.cn\/sxxjdc\/wp-content\/uploads\/sites\/19\/2023\/12\/image-1-300x143.png 300w\" sizes=\"(max-width: 703px) 100vw, 703px\" 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\u7535\u538b\u4f4e\u3001\u7a33\u5b9a\u6027\u5dee\uff0c\u56e0\u6b64 CIB \u7684\u5f00\u53d1\u4ecd\u5904\u4e8e\u8d77\u6b65\u9636\u6bb5\u3002<\/p>\n\n\n\n<p>\u8fc4\u4eca\u4e3a\u6b62\uff0c\u7814\u7a76\u8005\u4eec\u5728\u5f00\u53d1\u5177\u6709\u9ad8\u6bd4\u5bb9\u91cf\u548c\u7a33\u5b9a\u5faa\u73af\u6027\u80fd\u7684\u9634\u6781\u6750\u6599\u65b9\u9762\u5df2\u7ecf\u53d6\u5f97\u4e86\u521d\u6b65\u7684\u8fdb\u5c55\u3002\u4e0e\u6b64\u5f62\u6210\u9c9c\u660e\u5bf9\u6bd4\u7684\u662f\uff0c\u7531\u4e8e\u5f88\u96be\u5728\u5ba4\u6e29\u4e0b\u5b9e\u73b0 Ca<sup>2+<\/sup>\u7684\u53ef\u9006\u5b58\u50a8\uff0cCIB \u8d1f\u6781\u7684\u7814\u7a76\u8fdb\u5c55\u975e\u5e38\u7f13\u6162\u3002\u65e9\u671f\u7684\u7814\u7a76\u8868\u660e\uff0c\u53ea\u6709\u5728\u5408\u7406\u5b9a\u5236\u7684\u975e\u6c34\u7535\u89e3\u8d28\u4e2d\u624d\u80fd\u5b9e\u73b0\u9499\u91d1\u5c5e\u7684\u53ef\u9006\u7535\u9540\/\u5265\u79bb\u3002\u975e\u91d1\u5c5e\u786b\/\u78b3\uff08S\/C\uff09\u548c\u7852\uff08Se\uff09\u53ef\u4f5c\u4e3a\u6c34\u6027 CIB \u7684\u9633\u6781\u63d0\u4f9b\u8f83\u9ad8\u7684\u6bd4\u5bb9\u91cf\uff0c\u4f46\u5b83\u4eec\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u4f1a\u8fc5\u901f\u8870\u51cf\u3002\u6b64\u5916\uff0c\u6709\u673a\u7535\u6781\u6750\u6599\u7531\u4e8e\u5176\u73af\u4fdd\u6027\u3001\u53ef\u8bbe\u8ba1\u6027\u3001\u9ad8\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u6027\u3001\u53ef\u9006\u6027\u548c\u9ad8\u901f\u7387\u6027\u80fd\uff0c\u4e5f\u88ab\u7814\u7a76\u7528\u4f5c CIB \u7684\u9633\u6781\u3002\u7136\u800c\uff0c\u6709\u673a\u5c0f\u5206\u5b50\u5728\u6c34\u4f53\u7cfb\u4e2d\u4e25\u91cd\u6eb6\u89e3\uff0c\u800c\u4e14\u591a\u6570\u6709\u673a\u6750\u6599\u5b58\u50a8\u4e2d\u5176\u5bb9\u91cf\u7684\u5f88\u5927\u4e00\u90e8\u5206\u5f52\u56e0\u4e8e\u8d28\u5b50\u7684\u53c2\u4e0e\u3002\u4f46\u662f\uff0c\u5728\u5145\u7535\u548c\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0c\u968f\u7740\u8d28\u5b50\u7684\u5438\u9644\/\u8131\u9644\uff0c\u56fa\/\u6db2\u754c\u9762\u4e0a\u7684 pH \u503c\u4f1a\u53d1\u751f\u5267\u70c8\u6ce2\u52a8\uff0c\u4ece\u800c\u5bfc\u81f4\u7ed3\u6784\u8106\u5f31\u548c\u5faa\u73af\u6027\u80fd\u4e0d\u7406\u60f3\u3002\u53e6\u5916\uff0c\u76ee\u524d\u62a5\u9053\u7684\u6c34\u7cfb\u9499\u9633\u6781\u7684\u7535\u4f4d\u8303\u56f4\u4e3a-0.7-0 V\uff08vs. Ag\/AgCl\uff09\uff0c\u8fd9\u9650\u5236\u4e86\u9499\u79bb\u5b50\u5168\u7535\u6c60\u7684\u8f93\u51fa\u7535\u538b\u3002\u56e0\u6b64\uff0c\u6709\u5fc5\u8981\u8bbe\u8ba1\u7ed3\u6784\u7a33\u5b9a\u3001\u7535\u4f4d\u8f83\u4f4e\u7684\u66ff\u4ee3\u9633\u6781\u6750\u6599\uff0c\u4ee5\u9a71\u52a8\u7535\u538b\u533a\u95f4\u66f4\u5bbd\u548c\u6bd4\u80fd\u91cf\u66f4\u9ad8\u7684\u9499\u79bb\u5b50\u5168\u7535\u6c60\u3002<\/p>\n\n\n\n<p>\u57fa\u4e8e\u6b64\uff0c\u677e\u5c71\u6e56\u6750\u6599\u5b9e\u9a8c\u5ba4\u5415\u6d77\u660e\u526f\u7814\u7a76\u5458\u3001\u9999\u6e2f\u57ce\u5e02\u5927\u5b66\u652f\u6625\u4e49\u6559\u6388\u548c\u4e2d\u5357\u5927\u5b66\u5218\u950b\u526f\u6559\u6388\u56e2\u961f\u7684\u7814\u7a76\u4eba\u5458<strong>\u5f15\u5165\u4e86\u4e00\u79cd\u5177\u6709\u91cd\u590d\u5421\u55ea\u548c\u5421\u5576\u80fa\u5355\u5143\u7684\u5171\u4ef7\u6709\u673a\u9aa8\u67b6(PTHAT-COF)\uff0c\u7528\u4f5c\u6c34\u7cfbCIBs\u7684\u9633\u6781\u6750\u6599<\/strong>\u3002\u8fd9\u79cd\u521b\u65b0\u65b9\u6cd5\u4ea7\u751f\u4e86\u975e\u5e38\u5e73\u5766\u7684\u8d85\u4f4e\u7535\u4f4d\u5e73\u53f0\uff0c\u8303\u56f4\u4ece-0.6\u5230-1.05 V(vs. Ag\/AgCl)\uff0c\u8fd9\u5f52\u56e0\u4e8e\u8f83\u9ad8\u7684\u6700\u4f4e\u672a\u5360\u636e\u5206\u5b50\u8f68\u9053\u80fd\u7ea7\u3002\u6b64\u5916\uff0cPTHAT-COF\u8d1f\u6781\u8868\u73b0\u51fa\u51fa\u8272\u7684\u500d\u7387\u6027\u80fd(\u57281 A g<sup>-1<\/sup>\u4e0b152.3 mAh g<sup>-1<\/sup>)\u3001\u51fa\u8272\u7684\u957f\u671f\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u663e\u8457\u7684\u5bb9\u91cf\u4fdd\u6301\u7387(10000\u6b21\u5faa\u73af\uff0c\u4fdd\u6301\u738789.9%)\u3002\u5b9e\u9a8c\u548c\u7406\u8bba\u8ba1\u7b97\u5728\u5185\u7684\u673a\u7406\u7814\u7a76\u8868\u660e\uff0cC=N\u6d3b\u6027\u4f4d\u70b9\u5728\u653e\u7535\/\u5145\u7535\u8fc7\u7a0b\u4e2d\u901a\u8fc7\u5316\u5b66\u5438\u9644\u53ef\u9006\u5730\u6355\u83b7Ca<sup>2+<\/sup>\u79bb\u5b50\u3002PTHAT-COF\u5728\u6574\u4e2a\u5faa\u73af\u8fc7\u7a0b\u4e2d\u8868\u73b0\u51fa\u5353\u8d8a\u7684\u7ed3\u6784\u7a33\u5b9a\u6027\u3002\u6700\u540e\uff0c\u901a\u8fc7\u5c06PTHAT-COF\u4e0e\u9ad8\u538b\u9530\u57fa\u666e\u9c81\u58eb\u84dd\u9634\u6781\u914d\u5bf9\uff0c\u5b9e\u73b0\u4e86\u7535\u538b\u95f4\u9694\u4e3a2.2 V\u7684\u6c34\u7cfb\u5168CIB\uff0c\u8868\u73b0\u51fa\u975e\u51e1\u7684\u8010\u7528\u6027(10000\u6b21\u5faa\u73af\uff0c\u4fdd\u7559\u7387\u4e3a83.6%)\u3002\u8fd9\u9879\u7814\u7a76\u9610\u660e\u4e86\u6709\u673a\u9633\u6781\u6750\u6599\u5728\u6c34\u7cfb\u7535\u6c60\u4e2d\u5b9e\u73b0\u66f4\u9ad8\u7535\u6c60\u7535\u538b\u7684\u6f5c\u529b\u3002<\/p>\n\n\n\n<p>\u76f8\u5173\u6210\u679c\u4ee5\u201cA Pyrazine-Pyridinamine Covalent Organic Framework as a Low Potential Anode for Highly-durable Aqueous Calcium Ion Batteries\u201d\u4e3a\u9898\u5728\u56fd\u9645\u8457\u540d\u671f\u520a<em>Advanced Energy Materials<\/em>\u4e0a\u53d1\u8868\u3002\u8054\u5408\u57f9\u517b\u535a\u58eb\u738b\u6625\u82b3\u4e3a\u7b2c\u4e00\u4f5c\u8005\uff0c\u677e\u5c71\u6e56\u6750\u6599\u5b9e\u9a8c\u5ba4\u526f\u7814\u7a76\u5458\u5415\u6d77\u660e\uff0c\u9999\u6e2f\u57ce\u5e02\u5927\u5b66\u652f\u6625\u4e49\u6559\u6388\u548c\u4e2d\u5357\u5927\u5b66\u5218\u950b\u526f\u7814\u7a76\u5458\u4e3a\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff0c\u4e0a\u8ff0\u7814\u7a76\u5de5\u4f5c\u5f97\u5230\u4e86\u677e\u5c71\u6e56\u6750\u6599\u5b9e\u9a8c\u5ba4\u521b\u65b0\u6837\u677f\u5de5\u5382\u56e2\u961f\u9879\u76ee\u3001\u5e7f\u4e1c\u7701\u57fa\u7840\u4e0e\u5e94\u7528\u57fa\u7840\u57fa\u91d1\u7b49\u652f\u6301\u3002<\/p>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter\"><img decoding=\"async\" src=\"https:\/\/www.sslab.org.cn\/uploads\/%E7%A7%91%E7%A0%94%E8%BF%9B%E5%B1%95\/2023%E5%B9%B4\/20231116\/%E5%9B%BE%E7%89%87%202-800.jpg\" alt=\"\" \/><figcaption class=\"wp-element-caption\"><strong>\u56fe1\uff1aPTHAT-COF\u7684\u8868\u5f81:\u00a0<\/strong>a)\u7403\u68d2\u7ed3\u6784\u6a21\u578b\uff0cb)FT-IR\u5149\u8c31\uff0cc)N 1s\u5cf0\u7684XPS\u56fe\u6848\u3002d)\u91cd\u590d\u5355\u5143\u7684\u4f18\u5316\u7ed3\u6784\u548c\u8ba1\u7b97\u7684\u5206\u5b50\u8f68\u9053\u80fd\u7ea7\u3002e)\u8ba1\u7b97\u91cd\u590d\u5355\u5143\u7684MESP\u5206\u5e03\u3002f)FESEM\u548cg)TEM \u56fe\u50cf\u3002h)HAADF\u56fe\u50cf\u3002i)C\u5143\u7d20\u548cj)N\u5143\u7d20\u7684EDS\u6620\u5c04\u3002<\/figcaption><\/figure><\/div>\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter\"><img decoding=\"async\" src=\"https:\/\/www.sslab.org.cn\/uploads\/%E7%A7%91%E7%A0%94%E8%BF%9B%E5%B1%95\/2023%E5%B9%B4\/20231116\/%E5%9B%BE%E7%89%87%203-800.jpg\" alt=\"\" \/><figcaption class=\"wp-element-caption\"><strong>\u56fe2\uff1aPTHAT-COF\u4f5c\u4e3aCIB\u9633\u6781\u7684\u7535\u5316\u5b66\u548c\u52a8\u529b\u5b66\u6027\u80fd\uff1a<\/strong>a)20 mV s<sup>-1<\/sup>\u4e0b\u7684CV\u66f2\u7ebf\u3002b)PTHAT-COF\u4e0e\u5176\u4ed6\u8d1f\u6781\u6750\u6599\u5728\u6c34\u6027\u7535\u89e3\u8d28\u4e2d\u7684\u653e\u7535\/\u5145\u7535\u7535\u538b\u8303\u56f4\u7684\u6bd4\u8f83\u3002c)\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6bd4\u5bb9\u91cf\u548c\u76f8\u5e94\u7684\u5e93\u4ed1\u6548\u7387\u3002d)\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684GCD\u66f2\u7ebf\u3002e)\u9499\u7535\u6c60\u8d1f\u6781\u6bd4\u5bb9\u91cf\u6bd4\u8f83\u3002f)20 A g<sup>-1<\/sup>\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u3002g)0.2 mA\u65f6\u7684GITT\u66f2\u7ebf\u3002<\/figcaption><\/figure><\/div>\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter\"><img decoding=\"async\" src=\"https:\/\/www.sslab.org.cn\/uploads\/%E7%A7%91%E7%A0%94%E8%BF%9B%E5%B1%95\/2023%E5%B9%B4\/20231116\/%E5%9B%BE%E7%89%87%204-800.jpg\" alt=\"\" \/><figcaption class=\"wp-element-caption\"><strong>\u56fe3\uff1aPTHAT-COF\u4f5c\u4e3aCIBs\u9633\u6781\u57286.67 M CaCl<sub>2<\/sub>\u6c34\u6eb6\u6db2\u4e2d\u7684\u5b58\u50a8\u673a\u7406\uff1a<\/strong>a)\u4ee5PTHAT-COF\u4e3a\u5de5\u4f5c\u7535\u6781\u7684\u4e09\u7535\u6781\u539f\u4f4dpH\u6d4b\u8bd5\u88c5\u7f6e\u5145\u653e\u7535\u8fc7\u7a0b\u793a\u610f\u56fe\u3002b)\u524d\u4e24\u4e2a\u5faa\u73af\u671f\u95f4PTHAT-COF\u7535\u6781\u4e00\u4fa7\u7684\u539f\u4f4dpH\u53d8\u5316\u3002c)PTHAT-COF\u9633\u6781\u5728\u9971\u548cCaCl<sub>2<\/sub>\u00a0EG\u6eb6\u6db2\u4e2d\u57281 mV s<sup>-1<\/sup>\u4e0b\u524d\u56db\u4e2a\u5faa\u73af\u7684CV\u66f2\u7ebf\u3002d)PTHAT-COF\u5728\u9971\u548cCaCl<sub>2<\/sub>\u00a0EG\u6eb6\u6db2\u548c\u9971\u548cCaCl<sub>2<\/sub>\u6c34\u6eb6\u6db2\u4e2d\u57281 mV s<sup>-1<\/sup>\u4e0b\u7684CV\u6bd4\u8f83\u3002e)PTHAT-COF\u7535\u6781\u5728\u4e0d\u540c\u72b6\u6001\u4e0b\u7684FESEM\u56fe\u50cf\u3002f)PTHAT-COF\u7535\u6781\u5728\u7b2c\u4e8c\u653e\u7535\u72b6\u6001\u4e0b\u7684HAADF\u548cEDS\u56fe\u3002<\/figcaption><\/figure><\/div>\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter\"><img decoding=\"async\" src=\"https:\/\/www.sslab.org.cn\/uploads\/%E7%A7%91%E7%A0%94%E8%BF%9B%E5%B1%95\/2023%E5%B9%B4\/20231116\/%E5%9B%BE%E7%89%87%205-800.jpg\" alt=\"\" \/><figcaption class=\"wp-element-caption\"><strong>\u56fe4\uff1aPTHAT-COF\u8d1f\u6781\u7684\u7535\u8377\u5b58\u50a8\u673a\u5236\u7814\u7a76\uff1a<\/strong>a)PTHAT-COF\u8d1f\u6781\u57286.67 M CaCl<sub>2<\/sub>\u6c34\u7cfb\u7535\u89e3\u8d28\u4e2d\u4e0d\u540c\u5145\u653e\u7535\u6df1\u5ea6\u7684GCD\u66f2\u7ebf\u3002b)Ca 2p\u548cc)N 1s\u7684\u975e\u539f\u4f4dXPS\u5149\u8c31\u3002d)\u975e\u539f\u4f4dFT-IR\u5149\u8c31\u3002e)PTHAT-COF\u91cd\u590d\u5355\u5143\u5728\u653e\u7535\u8fc7\u7a0b\u4e2d\u7684\u7ed3\u6784\u6f14\u53d8\u3002<\/figcaption><\/figure><\/div>\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter\"><img decoding=\"async\" src=\"https:\/\/www.sslab.org.cn\/uploads\/%E7%A7%91%E7%A0%94%E8%BF%9B%E5%B1%95\/2023%E5%B9%B4\/20231116\/%E5%9B%BE%E7%89%87%206-800.jpg\" alt=\"\" \/><figcaption class=\"wp-element-caption\"><strong>\u56fe5\uff1a\u57fa\u4e8ePTHAT-COF\u9633\u6781\u548cMn-PBA\u9634\u6781\u7684\u5168CIB\u7535\u6c60\uff1a<\/strong>a)\u9499\u79bb\u5b50\u5168\u7535\u6c60\u53cd\u5e94\u673a\u7406\u793a\u610f\u56fe\u3002b)PTHAT-COF\u9633\u6781\u548cMn-PBA\u9634\u6781\u57280.5 mV s<sup>-1<\/sup>\u4e0b\u7684CV\u6bd4\u8f83\u3002c)\u5168\u7535\u6c60\u57280.5\u81f35 mV s<sup>-1<\/sup>\u626b\u63cf\u901f\u7387\u4e0b\u7684CV\u66f2\u7ebf\u3002d)\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u500d\u7387\u80fd\u529b\u3002e)\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684GCD\u66f2\u7ebf\u3002f)20 A g<sup>-1<\/sup>\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u3002g)\u5faa\u73af\u6027\u80fd\u6bd4\u8f83\u3002<\/figcaption><\/figure><\/div>\n\n\n<div class=\"wp-block-buttons is-layout-flex wp-block-buttons-is-layout-flex\">\n<div class=\"wp-block-button\"><a class=\"wp-block-button__link wp-element-button\" href=\"https:\/\/www.sslab.org.cn\/news\/researchdetail?id=23111619581342335AA132EA6\">\u539f\u6587\u94fe\u63a5<\/a><\/div>\n<\/div>\n","protected":false},"excerpt":{"rendered":"<p>\u8fc7\u53bb\u51e0\u5341\u5e74\u6765\uff0c\u6c34\u7cfb\u7535\u6c60\u56e0\u5176\u5b89\u5168\u6027\u9ad8\u3001\u6210\u672c\u4f4e\u3001\u73af\u4fdd\u3001\u53ef\u5feb\u901f\u5145\u7535\u7b49\u4f18\u70b9\u800c\u5907\u53d7\u5173\u6ce8\uff0c\u6210\u4e3a\u53ef\u9760\u7684\u5927\u89c4\u6a21\u50a8\u80fd\u6280\u672f\u7684\u7406\u60f3\u5019 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